(S)-(-)-2,2′-Bis(diphenylphosphino)-1,1′-binaphthyl Cas:76189-56-5

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(S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl

CAS NO.76189-56-5 (S)-(-)-2,2”-Bis(diphenylphosphino)-1,1”-binaphthyl Basic information

Product Name

(S)-(-)-2,2”-Bis(diphenylphosphino)-1,1”-binaphthyl

Synonyms

(S)-(-)-2,2”-Bis(diphenylphosphino)-1,1”-binaphthalene puriss.;2-(diphenylphosphino)-1-(2-(diphenylphosphino)naphthalen-1-yl)naphthalene;(S)-(-)-2,2”-Bis(diphenylphosphino)-1,1”-biphthyl;(S)-BINAP,99%e.e.;(S)-(-)-2,2”-Bis(diphenylphoshino)-1,1”-binaphthyl for synthesis;(+/-)-BINAP;BINAP;(+/-)-2,2”-BIS(DIPHENYLPHOSPHINO)-1,1”-BINAPHTHALENE

Structure

CAS NO

76189-56-5

Appearance

Crystals or Crystalline Powder

Assay

98%

MF:

C44H32P2

MW

622.67

EINECS

-0

Product Categories

BINAP Series;Chiral Phosphine;chiral;Chiral Reagents;Asymmetric Synthesis;Phosphine Ligands;Synthetic Organic Chemistry;Peptide;Chiral Compound;Aromatics;Catalyst

Storage

Shading, sealed, dry place.

Capacity

10000KG /month

Package

In paper drums /Fluoride drums /iron drums /plastic drums/IBC Tank ,etc.

Shipment method

By Sea ,Air ,Courier door to door ,etc.

Loading Port

China any port ,Beijing ,Shanghai ,Hong Kong etc.

Application

Chiral ligand for metal mediated asymmetric catalysis.

Organophosphorus Compounds

Diphosphines, sometimes called bisphosphanes, are organophosphorus compounds used as ligands in inorganic and organometallic chemistry. They are identified by the presence of two phosphino groups linked by a backbone, and are usually chelating.

Introduction of (S)-(-)-2,2”-Bis(diphenylphosphino)-1,1”-binaphthyl CAS NO.76189-56-5

The development of efficient chiral phosphorus ligands has played an important role in the development of asymmetric hydrogenation. Today, thousands of efficient chiral phosphorus

ligands with diverse structures have been developed, and their applications in asymmetric hydrogenation have been extensively utilized in both academic research and industry. The development of many efficient chiral phosphorus ligands also allows the discovery of new mechanistic information of Rh- or Ru-catalyzed asymmetric hydrogenation. The catalysts

are not restricted on those with Rh or Ru metals; complexes of other transition metals such as

Ir, Pt, Ti, Zr, and Pd are also effective. Numerous unsaturated compounds can be hydrogenated in

excellent ee’s using a metal catalyst associated with an appropriate chiral ligand.

Related chemicals of CAS NO.76189-56-5 (S)-(-)-2,2”-Bis(diphenylphosphino)-1,1”-binaphthyl

1.(R)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyli-tert-butylphosphine

CAS NO.158923-11-6

2.(1S)-1-(2-diphenylphosphanylcyclopentyl)-N,N-dimethyl-1-phenylmethanamine,iron

CAS NO.210842-74-3

3.(R)-1-[(SP)-2-(Di-tert-butylphosphino)ferrocenyl]ethylbis(2-methylphenyl)phosphine

CAS NO.849924-76-1

4.(S)-Ugi-Amine L-Tartrate CAS NO.111614-65-4

5.(R)-1-[(S)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine

CAS NO.155830-69-6



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